黄铁矿晶体形态标型在金矿评价中的意义   总被引：5，自引：0，他引：5  

初凤友  胡大千  于洪林  姚杰 《吉林大学学报(地球科学版)》2004,34(4):531-535

黄铁矿晶体形态是金矿床矿物学填图的良好指示参数之一.黄铁矿的微形貌特征具有指示其形成环境的意义.在金矿床中,早期成矿阶段结晶的a{100}或e{hk0}形态黄铁矿含金性较差;主成矿阶段形成的ae、aeo、ao、oa、oe等聚形晶,以及{310}、{320}等e黄铁矿含金性较好.黄铁矿形态沿矿体空间可以表现出分带性.其垂向分带趋势为:矿体上部以o{111}晶形为主,矿体中部以e{hk0}形为主,矿体下部主要以a{100}形占主导,或分别以其晶面发育的聚形为主.但不同矿床,甚至同一矿床的不同矿脉,这种分带的表现也不完全一致.因此,应用此分带模式进行深部矿体预测时,应具体情况具体分析.  相似文献   

Inorganic arsenic speciation in the waters of the Penzé estuary (NW France): Seasonal variations and fluxes to the coastal area     

Jennifer Vandenhecke  Matthieu Waeles  Jean-Yves Cabon  Cédric Garnier  Ricardo D. Riso 《Estuarine, Coastal and Shelf Science》2010

Over this one-year study, the variations of inorganic As species were examined monthly along the salinity gradient of the Penzé estuary (NW France) in relation with different biogeochemical parameters. In most cases, dissolved As exhibited a non-conservative behaviour which resulted from the competition between two major processes. In the upstream section of the estuary, a strong input of both total inorganic As and As(III) occurred. Then, the removal of the same species, under precipitation of iron oxides/oxyhydroxides, was observed in the low-salinity range (S < 10). Using our experimental data, the fluxes of the various As species were estimated for the first time in estuarine waters. Inputs from the river were mainly constituted of particulate As (∼70%). Conversely, dissolved species were predominant in the net fluxes (∼65%) and As(III) accounted for ∼15% of the dissolved net flux.  相似文献   

Geochemistry and genesis of authigenic pyrite from gas hydrate accumulation system in the Qilian Mountain permafrost,Qinghai, northwest China   总被引：2，自引：0，他引：2  

PingKang Wang  YouHai Zhu  ZhenQuan Lu  Xia Huang  ShouJi Pang  Shuai Zhang  ShaoQing Jiang  QingHai Li  KaiLi Yang  Bing Li 《中国科学:地球科学(英文版)》2014,57(9):2217-2231

A type of authigenic pyrites that fully fill or semi-fill the rock fractures of drillholes with gas hydrate anomalies are found in the Qilian Mountain permafrost; this type of pyrite is known as “fracture-filling” pyrite. The occurrence of “fracture-filling” pyrite has a certain similarity with that of the hydrate found in this region, and the pyrite is generally concentrated in the lower part of the hydrate layer or the hydrate anomaly layer. The morphology, trace elements, rare earth elements, and sulfur isotope analyses of samples from drillhole DK-6 indicate that the “fracture-filling” pyrites are dominated by cubic ones mainly aligned in a step-like fashion along the surfaces of rock fractures and are associated with a circular structure, lower Co/Ni and Sr/Ba, lower ΣREE, higher LREE, significant Eu negative anomalies, and Δ³⁴S_CDT positive bias. In terms of the pyrites’ unique crystal morphology and geochemical characteristics and their relationship with the hydrate layers or abnormal layers, they are closely related with the accumulation system of the gas hydrate in the Qilian Mountain permafrost. As climate change is an important factor in affecting the stability of the gas hydrate, formation of fracture-filling pyrites is most likely closely related to the secondary change of the metastable gas hydrate under the regional climate warming. The distribution intensity of these pyrites indicates that when the gas hydrate stability zone (GHSZ) is narrowing, the hydrate decomposition at the bottom of the GHSZ is stronger than that at the top of the GHSZ, whereas the hydrate decomposition within the GHSZ is relatively weak. Thus, the zone between the shallowest and the deepest distribution of the fracture-filling pyrite recorded the largest possible original GHSZ.  相似文献   

Sedimentary Environment and Mineralization of the Black Shale Polymetallic Layer in the Early Cambrian, SW China: Constraints from in situ LA-ICP-MS Analysis of Pyrite     

YANG Zhen  FU Yong  LI Chao  CAI Xi  GUO Chuan 《《地质学报》英文版》2024,98(2):416-429

A polymetallic layer is usually developed at the bottom of the early Cambrian black shale in Guizhou Province. The mineral that makes up the polymetallic layer is related to the sedimentary facies. To analyze the differentiation mechanism between polymetallic deposits (Ni-Mo and V), the Zhijin Gezhongwu profile located in the outer shelf and the Sansui Haishan V deposit located in the lower slope are selected to study the in situ sulfur isotopes and trace elements of pyrite. The results show that δ34S values of pyrite vary widely from ?7.8 ‰ to 28 ‰ in the Gezhongwu profile, while the δ34S values are relatively uniform (from 27.8 ‰ to 38.4 ‰) in the Haishan profile. The isotopic S composition is consistent with the transition that occurs in the sedimentary phase from the shelf to the deep sea on the transgressive Yangtze platform; this indicates that the δ34SO42? values in seawater must be differently distributed in depositional environments. The sulfur in the Ni-Mo layer is produced after the mixing of seawater and hydrothermal fluid, while the V layer mainly originates from seawater. Overall, the Ni-Mo and V deposits have been differentiated primarily on the basis of the combined effect of continental weathering and hydrothermal fluid.  相似文献   

吉林夹皮沟金矿带黄铁矿热电性及热爆裂特征   总被引：4，自引：2，他引：2  

张玙  袁万明  王庆飞  刘向伟  马楠  赵凯 《现代地质》2010,24(5):870-879

通过对夹皮沟金矿带主要载金矿物黄铁矿的热电性和热爆裂特征分析,确定了主成矿世代及各世代矿化类型,预测了深部探矿的可能性。黄铁矿以电子型(N型)为主,极少有空穴型(P型),N型热电系数分布于-347.3～-6.2 μV·℃-1,P型热电系数介于17.4～193.5 μV·℃-1, 成矿温度集中于258.8～319.2 ℃, 剥蚀率为50.260%～50.485%。爆裂曲线反映中低温(＜280 ℃)矿化没有高温(＞290 ℃)矿化好。综合分析认为,夹皮沟金矿带矿化分早期高温世代(热电系数峰值为-120 μV·℃-1,成矿温度峰值为320 ℃)和晚期中低温世代(热电系数值峰值为-210 μV·℃-1,成矿温度峰值为270 ℃)。前者包括石英脉型与蚀变岩型,在矿体走向与夹皮沟主断裂一致及相交的矿区中均有发育;后者属石英脉型,主要在矿体走向与夹皮沟主断裂相交的矿区发育,叠加于高温世代热液矿化之上。高温热液矿化世代是主成矿世代,但有叠加的部位矿化增强。  相似文献   

有孔虫壳体内草莓状黄铁矿成因及其地质意义——以湖北雁门口地区栖霞组有孔虫化石为例   总被引：1，自引：0，他引：1  

李洪星  陆现彩  边立曾  许伟伟  李娟  张壮志  赵华平  宫红良 《高校地质学报》2009,15(4):470

在湖北省京山县雁门口地区栖霞组上部的含泥灰岩中存在丰富的节房虫科底栖有孔虫化石,主要有节房虫属、厚壁虫属和郎格虫属,壳体均被草莓状黄铁矿充填。对其系统的显微镜、扫描电镜观察和黄铁矿的能谱分析结果发现,黄铁矿草莓体直径最大为15 μm,平均约10 μm,硫铁原子比值（S/Fe）为1.90±0.10,表明在黄铁矿形成过程中,有孔虫壳体空腔内呈轻度- 中度贫氧的微环境。在分析该类黄铁矿成因的基础上,认为有孔虫壳体内的黄铁矿在指示沉积环境和保存环境方面具有局限性。  相似文献   

贵州锦丰（烂泥沟）金矿床含砷黄铁矿和脉石英及其包裹体的微量元素特征   总被引：5，自引：0，他引：5  

胡瑛  陈懋弘  董庆吉  黄庆文 《高校地质学报》2009,15(4):506

贵州锦丰（烂泥沟）金矿是滇黔桂“金三角”目前已探明最大的卡林型金矿床。含砷黄铁矿是该矿床最主要的载金矿物,硅化及石英脉是最显著的热液蚀变类型。本文采用高精度电感耦合等离子质谱（ICP-MS）对含砷黄铁矿和脉石英及其包裹体的微量元素进行了测试,结果表明含砷黄铁矿富亲硫元素,并相对于围岩和上部地壳均强烈富集;亏损V,Sr 及高场强元素。同生黄铁矿也具有类似的特征。脉石英除亲石元素含量高以外,还表现为亲硫元素以及Mo,Bi 含量较高。但与上部地壳相比,绝大部分元素贫化。相应包裹体的微量元素含量普遍低于单矿物,但变化特征一致。结合矿物和包裹体的稀土元素分析,发现脉石英和含砷黄铁矿及其包裹体均表现为HFSE明显亏损,Th/La,Nb/La 比值小于1,说明成矿流体为富Cl 的流体。含砷黄铁矿及其包裹体中Co/Ni 比值远小于1,反映成矿温度较低,推测成矿流体主要来源于以沉积建造水为主的盆地流体。  相似文献   

广西北部湾地区表层土壤As分布特征及其影响因素     

郑国东  覃建勋  付伟  杨志强  赵辛金  卢炳科 《吉林大学学报(地球科学版)》2018,48(1):181-192

选取广西北部湾地区表层土壤中As元素为研究对象,采集了7 327个土壤样品,400个岩石样品,分析As、K₂O、Na₂O、CaO、MgO、SiO₂、Al₂O₃、TFe₂O₃、Mn、Ti、pH和有机碳（SOC）等指标,探讨了土壤成土母岩、成土作用、土壤组成、pH和有机质等对表层土壤As元素的影响。结果表明：As元素平均质量分数为7.96×10^-6,为中国土壤背景值0.80倍;风化作用对于As元素的次生富集起到极为重要的作用,明显强于成土母岩As元素背景的影响。Pearson相关分析和主成分分析表明：在土壤组成和土壤性质等因素中,含Al矿物（Al₂O₃）、含Fe矿物（TFe₂O₃）、含Si矿物（SiO₂）和SOC,对土壤As的富集起到主导作用;pH 和含 Ca矿物（CaO）的作用较弱;而含K矿物（K₂O）、含Na矿物（Na₂O）和含Mg矿物（MgO）对As的次生富集作用可以忽略不计。  相似文献   

广西龙头山金矿床黄铁矿标型特征及其地质意义          下载免费PDF全文

陶诗龙  赖健清  张建东  胡理芳  钱丽华 《地质找矿论丛》2017,32(1):33-41

广西龙头山金矿床是大瑶山成矿带内重要的金矿床,矿区发育大量不同类型的黄铁矿。根据黄铁矿的产出特征,将黄铁矿划分为5个世代,对应着5个成矿阶段:电气石-石英-硫化物阶段(Ⅰ)、石英-黄铁矿-黄铜矿阶段(Ⅱ)、石英-多金属硫化物阶段(Ⅲ)、石英-黄铁矿-闪锌矿阶段(Ⅳ)、石英-黄铁矿阶段(Ⅴ)。不同阶段黄铁矿晶形均以{100}为主,少见{210};金含量与{210}含量呈正相关。黄铁矿晶胞参数为5.411 86~5.415 52,变化幅度不大,与钴含量呈正相关,主成矿阶段受金含量影响而变大。形貌及砷含量变化特征表明,{210}和金含量随砷含量降低而升高,说明砷含量降低利于{210}的出现,且金与砷不存在正相关关系。形貌特征及微量元素特征均反映主成矿阶段温度应220℃,且多集中于300℃的范围;δFe—δS图解及矿床地质特征表明,成矿热液主要为岩浆热液。综合分析认为,龙头山金矿床为中-高温岩浆期后热液矿床。  相似文献   

个旧锡矿东区黄铁矿成分标型特征研究          下载免费PDF全文

曾茜  陈守余  赵江南 《地质找矿论丛》2017,32(3):375-384

黄铁矿是个旧锡矿最常见的硫化物之一,但对其相关研究比较匮乏。本文通过对个旧锡矿东区不同类型矿体中黄铁矿的主微量元素特征研究获取黄铁矿成分的标型特征。个旧锡矿东区其矿体分为层间氧化残余硫化矿、接触带矽卡岩矿体、脉状矿、变基性火山岩矿体四类,不同类型黄铁矿产出特征各异,如层间氧化矿残余硫化矿中黄铁矿具有典型的残余结构,矽卡岩矿体中黄铁矿具有压碎结构、骸晶结构等。研究数据表明,黄铁矿总体表现亏铁、富硫,富集Pb、Zn、Cu、Cd、In、As、Sb、Bi、Sn、Ag、Au、W等元素,贫Co、Ni、Cr、Te、Se元素,Co/Ni较大。层间氧化矿残余硫化矿与变基性火山岩两类产于层间的矿体成矿环境硫逸度较高,矽卡岩矿体中黄铁矿高温元素含量较高,脉状矿中黄铁矿微量元素总量较高。硫逸度越大,温度越低,越有利于As进入黄铁矿晶格。成矿元素物源丰富,As、Ag、Au很可能来源于地层,Pb则来源于岩浆,Bi可能大部分来源于酸性岩浆。温度和共生矿物是影响黄铁矿中微量元素富集的重要因素,共生黄铁矿-黄铜矿可以指示形成时的温压条件。本区黄铁矿属中低温成矿,从高到低依次为矽卡岩矿—层间氧化矿残余硫化矿—变基性火山岩矿—脉状矿。来自岩浆的成矿物源较丰富,以及产于岩体边缘蚀变岩型矿体的发现,可推测岩体内部矿产资源丰富。  相似文献